Chemical Innovations in Sustainable Agriculture

This review examines current chemical advances in agriculture, with a focus on fertilizer and pesticide research to improve crop production, environmental sustainability, and global food security via new, interdisciplinary techniques.

Agriculture

I. Introduction to Agricultural Chemistry

Chemistry contributes significantly to agricultural productivity through a variety of means, including soil chemistry, nutrient management, and the creation of agrochemicals. Interdisciplinary collaboration between chemistry and agriculture is critical in tackling food security issues. Modern agricultural methods mainly rely on agrochemicals for insect control, disease management, and weed elimination (Jeschke, 2015). The use of nanotechnology in agriculture has created new prospects for increasing crop yield by developing nanopesticides and nanofertilizers. Nanotechnology-based delivery systems provide regulated release profiles that can improve the efficiency of pesticide applications (Chaud et al., 2021).

Furthermore, the development of nanoparticles has enabled targeted distribution of agrochemicals, resulting in accurate and efficient agricultural application (Wang et al., 2023). Polyphenols and metal-organic frameworks in pesticide formulations can enhance crop protection and promote growth (Wang et al., 2023; Rodríguez-Diéguez & Horcajada, 2022). Furthermore, the use of polymers in agriculture, such as controlled-release agrochemicals and superabsorbents, has aided technological progress (Milani et al., 2017).

However, indiscriminate use of agrochemicals endangers human health and the environment (Sekhotha et al., 2016; Ji et al., 2021). Studies have demonstrated that pesticide exposure can have negative health consequences, highlighting the significance of effective safety precautions and education for agricultural workers (Sekhotha et al., 2016; Kaewkerd et al., 2022). The development of sustainable agricultural techniques, such as the use of botanical insecticides and lignocellulosic-based nanopesticides, provides opportunities to reduce environmental effect while preserving agricultural output (Campos et al., 2019; Lima et al., 2021).

Integrating chemistry into agriculture is critical for tackling global food security issues. Advances in nanotechnology, polymer science, and material engineering have transformed the creation and application of agrochemicals, providing novel options for sustainable agriculture. To preserve the long-term survival of agricultural systems, the benefits of agrochemicals must be balanced against environmental and health concerns.

II. Innovations in Fertilizer Development

Chemistry contributes significantly to agricultural productivity through a variety of means, including soil chemistry, nutrient management, and the creation of agrochemicals. Interdisciplinary collaboration between chemistry and agriculture is critical in tackling food security issues. Modern agricultural methods mainly rely on agrochemicals for insect control, disease management, and weed elimination (Jeschke, 2015). The use of nanotechnology in agriculture has created new prospects for increasing crop yield by developing nanopesticides and nanofertilizers. Nanotechnology-based delivery systems provide regulated release profiles that can improve the efficiency of pesticide applications (Chaud et al., 2021).

Furthermore, the development of nanoparticles has enabled targeted distribution of agrochemicals, resulting in accurate and efficient agricultural application (Wang et al., 2023). Polyphenols and metal-organic frameworks in pesticide formulations can enhance crop protection and promote growth (Wang et al., 2023; Rodríguez-Diéguez & Horcajada, 2022). Furthermore, the use of polymers in agriculture, such as controlled-release agrochemicals and superabsorbents, has aided technological progress (Milani et al., 2017).

However, indiscriminate use of agrochemicals endangers human health and the environment (Sekhotha et al., 2016; Ji et al., 2021). Studies have demonstrated that pesticide exposure can have negative health consequences, highlighting the significance of effective safety precautions and education for agricultural workers (Sekhotha et al., 2016; Kaewkerd et al., 2022). The development of sustainable agricultural techniques, such as the use of botanical insecticides and lignocellulosic-based nanopesticides, provides opportunities to reduce environmental effect while preserving agricultural output (Campos et al., 2019; Lima et al., 2021).

Integrating chemistry into agriculture is critical for tackling global food security issues. Advances in nanotechnology, polymer science, and material engineering have transformed the creation and application of agrochemicals, providing novel options for sustainable agriculture. To preserve the long-term survival of agricultural systems, the benefits of agrochemicals must be balanced against environmental and health concerns.

III. Pesticides and Crop Protection

Pesticide development has evolved from traditional chemical pesticides to biopesticides and genetically altered crops, driven by the desire for safer and more effective pest management measures to encourage sustainable agricultural practices. Biopesticides originating from natural sources such as plants, microbes, and animals are gaining popularity as alternatives to synthetic pesticides due to their lower environmental effect and risk to human health (Czaja et al., 2014; Nascimento et al., 2021).

Chemical innovations have played an important part in the development of biopesticides, with studies focused on essential oils from Bursera morelensis and Lippia graveolens to create new biopesticides for postharvest control (Medina-Romero et al., 2021). Encapsulation techniques utilizing supercritical CO2 have been investigated as a means to improve the efficacy of biopesticides, with potential uses for pest management (Nascimento et al., 2021). Furthermore, microbial biopesticides, such as viruses, bacteria, fungus, algae, and nematodes, have showed promise in pest management tactics (Nidhi et al., 2022).

Despite the benefits of biopesticides, farmers face hurdles in adopting them. Cost and perceived effectiveness are important factors in farmers’ decisions to use biopesticides instead of chemical pesticides (Constantine et al., 2020; Guo et al., 2021). According to studies, improved knowledge and education among farmers about the benefits of biopesticides is required to boost their adoption and incorporation into pest control techniques (Guo et al., 2021).

The regulatory landscape for biopesticides differs widely, with places such as the European Union (EU) implementing special laws to assure their safety and efficacy (Ashaolu et al., 2022). The development of sustainable nano-pesticide platforms, such as those based on Pyrethrins II, offers the potential for innovative pest preventive and control solutions while reducing environmental effect (Liu et al., 2022).

To summarize, the advent of biopesticides represents a viable route for sustainable pest management in agriculture. Biopesticides, which leverage chemical research and technology breakthroughs, provide effective alternatives to traditional chemical pesticides, contributing to environmentally responsible and health-conscious pest management tactics.

References:

Ashaolu, C., Okonkwo, C., Njuguna, E., & Ndolo, D. (2022). Recommendations for effective and sustainable regulation of biopesticides in nigeria. Sustainability, 14(5), 2846. https://doi.org/10.3390/su14052846

Campos, E., Proença, P., Oliveira, J., Bakshi, M., Abhilash, P., & Fraceto, L. (2019). Use of botanical insecticides for sustainable agriculture: future perspectives. Ecological Indicators, 105, 483-495. https://doi.org/10.1016/j.ecolind.2018.04.038

Chaud, M., Souto, E., Zielińska, A., Severino, P., Batain, F., Oliveira‐Júnior, J., … & Alves, T. (2021). Nanopesticides in agriculture: benefits and challenge in agricultural productivity, toxicological risks to human health and environment. Toxics, 9(6), 131. https://doi.org/10.3390/toxics9060131

Chen, F., Lü, S., Gao, C., Wang, X., Xu, X., Bai, X., … & Wu, L. (2015). “smart” fertilizer with temperature- and ph-responsive behavior via surface-initiated polymerization for controlled release of nutrients. Acs Sustainable Chemistry & Engineering, 3(12), 3157-3166. https://doi.org/10.1021/acssuschemeng.5b01384

Constantine, K., Kansiime, M., Mugambi, I., Nunda, W., Chacha, D., Rware, H., … & Day, R. (2020). Why don’t smallholder farmers in kenya use more biopesticides?. Pest Management Science, 76(11), 3615-3625. https://doi.org/10.1002/ps.5896

Czaja, K., Góralczyk, K., Struciński, P., Hernik, A., Korcz, W., Minorczyk, M., … & Ludwicki, J. (2014). Biopesticides – towards increased consumer safety in the european union. Pest Management Science, 71(1), 3-6. https://doi.org/10.1002/ps.3829

Dutta, S., Pal, S., Panwar, P., Sharma, R., & Bhutia, P. (2022). Biopolymeric nanocarriers for nutrient delivery and crop biofortification. Acs Omega, 7(30), 25909-25920. https://doi.org/10.1021/acsomega.2c02494

Fellet, G., Pilotto, L., Marchiol, L., & Braidot, E. (2021). Tools for nano-enabled agriculture: fertilizers based on calcium phosphate, silicon, and chitosan nanostructures. Agronomy, 11(6), 1239. https://doi.org/10.3390/agronomy11061239

Guo, H., Sun, F., Pan, C., Yang, B., & Li, Y. (2021). The deviation of the behaviors of rice farmers from their stated willingness to apply biopesticides—a study carried out in jilin province of china. International Journal of Environmental Research and Public Health, 18(11), 6026. https://doi.org/10.3390/ijerph18116026

Jeschke, P. (2015). Progress of modern agricultural chemistry and future prospects. Pest Management Science, 72(3), 433-455. https://doi.org/10.1002/ps.4190

Ji, Y., Ma, S., Lv, S., Wang, Y., Lü, S., & Liu, M. (2021). Nanomaterials for targeted delivery of agrochemicals by an all-in-one combination strategy and deep learning. Acs Applied Materials & Interfaces, 13(36), 43374-43386. https://doi.org/10.1021/acsami.1c11914

Kaewkerd, O., Thiengtham, S., Panput, A., Dankasai, C., Kempanya, P., & Muenhor, C. (2022). Health and agrochemical use experiences of agricultural workers with high serum cholinesterase levels in northeastern thailand. Journal of Public Health and Development, 20(3), 283-295. https://doi.org/10.55131/jphd/2022/200322

Kottegoda, N., Sandaruwan, C., Priyadarshana, G., Siriwardhana, A., Rathnayake, U., Arachchige, D., … & Amaratunga, G. (2017). Urea-hydroxyapatite nanohybrids for slow release of nitrogen. Acs Nano, 11(2), 1214-1221. https://doi.org/10.1021/acsnano.6b07781

Lima, P., Antunes, D., Forini, M., Pontes, M., Mattos, B., & Grillo, R. (2021). Recent advances on lignocellulosic-based nanopesticides for agricultural applications. Frontiers in Nanotechnology, 3. https://doi.org/10.3389/fnano.2021.809329

Liu, X., Yang, Y., Gao, B., Li, Y., & Wan, Y. (2017). Environmentally friendly slow-release urea fertilizers based on waste frying oil for sustained nutrient release. Acs Sustainable Chemistry & Engineering, 5(7), 6036-6045. https://doi.org/10.1021/acssuschemeng.7b00882

Liu, Y., Wang, G., Qin, Y., Chen, L., Zhou, C., Qiao, L., … & Ji, Y. (2022). Sustainable nano-pesticide platform based on pyrethrins ii for prevention and control monochamus alternatus. Journal of Nanobiotechnology, 20(1). https://doi.org/10.1186/s12951-022-01409-6

Medina-Romero, Y., Hernandez-Hernandez, A., Rodriguez-Monroy, M., & Canales-Martinez, M. (2021). Essential oils of bursera morelensis and lippia graveolens for the development of a new biopesticides in postharvest control. Scientific Reports, 11(1). https://doi.org/10.1038/s41598-021-99773-0

Milani, P., França, D., Balieiro, A., & Faez, R. (2017). Polymers and its applications in agriculture. Polímeros, 27(3), 256-266. https://doi.org/10.1590/0104-1428.09316

Nascimento, D., Albuquerque, E., & Melo, S. (2021). Biopesticide encapsulation using supercritical co2: a comprehensive review and potential applications. Molecules, 26(13), 4003. https://doi.org/10.3390/molecules26134003

Nidhi, .., Mushtaq, S., Saji, G., & Gupta, V. (2022). Mode of action of biopesticides against pests and future prospects of biopesticides and nanobiopesticides. Journal of Advanced Scientific Research, 13(11), 01-08. https://doi.org/10.55218/jasr.2022131101

Rodríguez-Diéguez, A. and Horcajada, P. (2022). Metal–organic frameworks in agriculture. Acs Applied Materials & Interfaces, 14(15), 16983-17007. https://doi.org/10.1021/acsami.2c00615

Sekhotha, M., Monyeki, K., & Sibuyi, M. (2016). Exposure to agrochemicals and cardiovascular disease: a review. International Journal of Environmental Research and Public Health, 13(2), 229. https://doi.org/10.3390/ijerph13020229

Seleiman, M., Almutairi, K., Alotaibi, M., Shami, A., Alhammad, B., & Battaglia, M. (2020). Nano-fertilization as an emerging fertilization technique: why can modern agriculture benefit from its use?. Plants, 10(1), 2. https://doi.org/10.3390/plants10010002

Skrzypczak, D., Jarzembowski, Ł., Izydorczyk, G., Mikula, K., Hoppe, V., Mielko, K., … & Witek-Krowiak, A. (2021). Hydrogel alginate seed coating as an innovative method for delivering nutrients at the early stages of plant growth. Polymers, 13(23), 4233. https://doi.org/10.3390/polym13234233

Wang, C., Qin, J., & Yang, Y. (2023). Multifunctional metal–organic framework (mof)-based nanoplatforms for crop protection and growth promotion. Journal of Agricultural and Food Chemistry. https://doi.org/10.1021/acs.jafc.3c01094

Wang, R., Liu, S., & Ma, Z. (2023). Recent development of versatile polyphenol platforms in fertilizers and pesticides. Journal of Agricultural and Food Chemistry, 71(25), 9599-9608. https://doi.org/10.1021/acs.jafc.3c01952

Xiang, Y., Ru, X., Shi, J., Song, J., Zhao, H., Liu, Y., … & Lu, X. (2017). Preparation and properties of a novel semi-ipn slow-release fertilizer with the function of water retention. Journal of Agricultural and Food Chemistry, 65(50), 10851-10858. https://doi.org/10.1021/acs.jafc.7b03827

Yuvaraj, M. and Subramanian, K. (2021). Carbon sphere-zinc sulphate nanohybrids for smart delivery of zinc in rice (oryza sativa l). Scientific Reports, 11(1). https://doi.org/10.1038/s41598-021-89092-9

Leave a Reply

Your email address will not be published. Required fields are marked *